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   Shrinking While Heated (Physics)
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   Author  Topic: Shrinking While Heated (Physics)  (Read 531 times)
Barukh
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Shrinking While Heated (Physics)  
« on: Jul 4th, 2005, 9:10am »
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Is it possible that a solid substance shrinks when its temperarture rises? Assume there is no change in pressure.
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JocK
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Re: Shrinking While Heated (Physics)  
« Reply #1 on: Jul 4th, 2005, 10:05am »
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the answer is yes (see e.g. http://physics.ucsc.edu/research/zs.html).
 
 
 
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solving abstract problems is like sex: it may occasionally have some practical use, but that is not why we do it.

xy - y = x5 - y4 - y3 = 20; x>0, y>0.
baddab457
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Re: Shrinking While Heated (Physics)  
« Reply #2 on: Jul 4th, 2005, 5:14pm »
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shrink wrap..  Grin
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"Dont Die For Your Country, Make Them SoB's Die For Theres" G Paton
Bob Purcell
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Re: Shrinking While Heated (Physics)  
« Reply #3 on: Jul 5th, 2005, 7:25pm »
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Ice  
 
Rap
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Noke Lieu
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pen... paper... let's go! (and bit of plastic)

   
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Re: Shrinking While Heated (Physics)  
« Reply #4 on: Jul 5th, 2005, 7:52pm »
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A steak on the barbie. Cheesy
 
But there would be a difference in the turgour pressure of the cells.  Sad
 
And the pressure from your peers to cook it perfectly, but without being seen to fuss over it Cool
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a shade of wit and the art of farce.
JocK
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Re: Shrinking While Heated (Physics)  
« Reply #5 on: Jul 6th, 2005, 10:07am »
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on Jul 5th, 2005, 7:25pm, Bob Purcell wrote:
Ice  
 
Rap

 
Don't think that is correct. Ice has a positive thermal expansion coefficient.
 
Now, if you allow for a phase transition (from ice into water) or simply consider liquified ice (water in the temperature interval of 0-4 degC), you will observe negative thermal expansion. The question, however, asks us to restrict ourselves to solids.
 
 
 
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solving abstract problems is like sex: it may occasionally have some practical use, but that is not why we do it.

xy - y = x5 - y4 - y3 = 20; x>0, y>0.
SWF
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Re: Shrinking While Heated (Physics)  
« Reply #6 on: Jul 6th, 2005, 7:40pm »
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Starting at a low enough temperature silica will shrink when heated.  Zirconia shows a sudden volume decrease at an elevated temperature due to a (solid state) phase change, as do other solids. The alloy Invar (64 Fe-36 Ni) has near zero, and possibly slightly negative, thermal expansion over a fairly wide range of temperature. Graphite fibers often have negative thermal expansion along the axis of the fiber.
 
Related to this topic: one of the Maxwell thermodynamic relations says that derivative of volume with respect to temperature at constant pressure equals the negative of the derivative of entropy with respect to pressure at constant temperature.
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Barukh
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Re: Shrinking While Heated (Physics)  
« Reply #7 on: Jul 6th, 2005, 11:48pm »
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Wow! So many interesting examples from JocK and SWF!
 
When asking this question, I was aware just of a single example - a certain crystallographic phase of pure plutonium. Look here for the nice graphs.
 
SWF, could you please provide references for your examples?
 
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